ISSN:
1572-8927
Schlagwort(e):
Actinides
;
thermodynamic data
;
Pitzer ion–interaction parameters
;
trivalent actinides
;
tetravalent actinides
;
pentavalent actinides
;
hexavalent actinides
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract A review of the applicability of Pitzer's equations to the aqueous thermodynamics of actinide species in natural waters is presented. This review includes a brief historical perspective on the application of Pitzer's equations to actinides, information on the difficulties and complexities of studying and modeling the different actinide oxidation states, and a discussion of the use of chemical analogs for different actinide oxidation states. Included are tables of Pitzer ion–interaction parameters and associated standard state equilibrium constants for each actinide oxidation state. These data allow the modeling of the aqueous thermodynamics of different actinide oxidation states to high ionic strength.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1022630931742
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