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  • Polymer and Materials Science  (4)
  • carbon black  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 1847-1856 
    ISSN: 0887-6266
    Keywords: electrical transport ; dielectric properties ; barium titanate ; carbon black ; epoxy resin ; relaxation processes ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Conductivity and dielectric constant of a three-component 0-3 composite of epoxy resin-barium titanate-carbon black (0-3 composites are systems in which the filler is in the form of 0-dimensional (point-like, disperse) particles in a three-dimensional polymeric matrix1) have been investigated both at DC and the frequency range of 20-106 c/s. The effect of barium titanate concentration on percolation threshold, critical indices and the mechanism of conduction has been examined. An attempt was made to describe the electrical properties of composites with models originally developed for two-component systems' dielectric-conductor. With increasing barium titanate concentration the agreement of experimentally found frequency dependencies of conductivity and dielectric constant with models based on Debye's equation was found to degrade. An adequate description of electrical properties of composites' dielectric-ferroelectric-conductor should be based on the Havriliak-Negami equation. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1847-1856, 1998
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 489-499 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal and current noise in carbon black-filled polystyrene and polyethylene was studied in the vicinity of Tg and Tm. A highly conductive grade of carbon black was used (Ketjenblack EC): 4% for PS and 6.5% for PE. Pronounced maxima in noise voltage were found at Tg for PS and Tm for PE. Prolonged storage at T lower than Tg enhanced the intensity of the noise peak at Tg for PS. A hysteresis occurred on cooling after a heating cycle, with the current and thermal noise being lower on the cooling cycle (no maximum in the case of PS). The peak temperature was lower for PE on the cooling cycle. Good agreement was found between experimental and calculated thermal noise values. The thermal noise spectra were white within the temperature range of 20° to 140°C. The appearance of the current noise peaks could be associated with a conduction model where a decrease in the number of contact points in the carbon black network occurs in the transition regions. This is in accordance with the concept proposed earlier that the carbon black network existing in a polymer undergoes a rearrangement when the polymer melts (softens) or solidifies.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 831-845 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Pronounced maxima in resistivity-temperature curves have been found at or above Tg for a number of amorphous polymers (PS, PMMA, PVC) containing a small percentage of carbon black. The maxima appeared only after a certain period of storage at T 〈 Tg or at heating rates substantially higher than those used in cooling the samples prior to the measurement. For this reason, no maxima were observed during cooling. In crystalline polymers (PE, PP), maxima at Tm appeared both on heating and cooling. Marked relaxation effects (time-dependent resistivity) were recorded in the Tg and Tm regions. Good agreement was found between resistivity and thermal noise data.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 14 (1976), S. 1157-1160 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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