ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Pronounced maxima in resistivity-temperature curves have been found at or above Tg for a number of amorphous polymers (PS, PMMA, PVC) containing a small percentage of carbon black. The maxima appeared only after a certain period of storage at T 〈 Tg or at heating rates substantially higher than those used in cooling the samples prior to the measurement. For this reason, no maxima were observed during cooling. In crystalline polymers (PE, PP), maxima at Tm appeared both on heating and cooling. Marked relaxation effects (time-dependent resistivity) were recorded in the Tg and Tm regions. Good agreement was found between resistivity and thermal noise data.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1975.070190319
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