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  • Polymer and Materials Science  (8)
  • thermal expansion  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 4 (1966), S. 777-788 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The structure of polypropylene crystallized at pressures up to 5000 atm. has been studied. Upon slow cooling from the melt at 320 atm., the γ modification, previously found only in low molecular weight and stereoblock fractions, begins to appear in small amounts in addition to the normal α monoclinic form. As the pressure is increased further, a larger proportion of the sample crystallizes in the γ form until, at 5000 atm., only the γ modification is present. X-ray and DTA studies show that the γ form of polypropylene transforms to the normal α modification at a temperature only slightly below the γ melting point. Evidence is presented which favors the occurrence of a solid-state transition as a model of transformation to the α form. Results from isothermal crystallizations at low supercoolings and annealing experiments under high pressure show that the melting point of the γ modification of polypropylene is very sensitive to crystallite perfection.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Two linear polyethylene fractions (Mη, 11,260 and 100,000) and mixtures of these fractions have been isothermally crystallized from the melt under pressures up to 3000 atm. Characterization of individually crystallized fractions with transmission electron microscopy indicates that pressure can be used to produce a crystallite whose thickness is a measure of the chain length within it. Although the high molecular weight fraction yields spherulites containing individually varying lamellae thicknesses, the maximum thickness of each lamella is a measure of the chain length within it. Both electron micrographs and differential thermal analysis results show that crystallization of homogeneous mixtures of the high and low molecular weight fractions under high pressure results in a distinct fractionation and segregation according to molecular weight.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 547-557 
    ISSN: 0887-6266
    Keywords: thermal expansion ; crystalline polymers ; dimensional stability ; molecular composite model ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dimensional stability of crystalline polymers such as polyethylene and polypropylene is a critical property in structural applications requiring known dimensional stability. It is essential to evaluate how such structural systems will respond when exposed to thermal fluctuations. Utilizing the molecular composite approach, oriented polyethylene has been modeled as a macroscopic composite of its constituent crystalline and amorphous phases. The molecular composite model, originally developed to describe the isotropic behavior of crystalline polymers, has been refined to account for the anisotropic micromorphological behavior of oriented polyethylene solids. This refinement accounts for the deformation and orientation of both constituent phases; the variation of the amorphous phase mechanical and expansional properties due to the taut tie molecules has likewise been considered. Furthermore, a theoretical expression relating the crystalline orientation descriptors, λ and fc, has been developed. A detailed calculational format for the prediction of the expansivity of oriented polyethylene is outlined. The overall pattern of anisotropic dimensional behavior has been correctly predicted when compared with experimentally measured thermal expansivities of various types of polyethylene. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 3041-3055 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Synthetic polymer biomaterials being considered for cardiovascular applications must perform under conditions of large cyclic deformations for long lifetimes. In designing with these materials and eventually qualifying them clinically, it would be extremely helpful to be able to predict the fatigue lifetimes accurately and reliably. In this article a calculational format is presented which predicts the lifetime distribution function for elastomeric sheets undergoing tension-tension fatigue. From a knowledge of the intrinsic tensile strength distribution and the effect of an “equivalent” edge flaw size on the tensile strength, the inherent flaw size distribution is determined. A tearing energy concept is utilized to determine the flaw growth law constants. Each of these three short-term tests provides a pair of constants which, taken together, permit calculation of the fatigue lifetime distribution. When compared using Kolmogoroff statistics, experimental tensile-tensile fatigue results at 0.01 cps agreed well with the theoretically predicted lifetime distribution function.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The processes of sorption and diffusion of water in anisotropic glass ribbon-reinforced composite films of controlled structural and physical characteristics were investigated in terms of the film properties, e.g., geometry, orientation, and volume fraction of the filler; molding characteristics of the composite film; and the adhesion between the glass ribbon and continuous cellulose acetate matrix. While the diffusion of water through unfilled cellulose acetate film was found to be a simple activated process with very little concentration dependence, the diffusion behavior of glass ribbon-reinforced cellulose acetate was found to be anomalous and concentration dependent.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 12 (1974), S. 1239-1243 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 4 (1966), S. 453-458 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 12 (1974), S. 161-165 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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