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  • Polymer and Materials Science  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 28 (1990), S. 1015-1031 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Static and dynamic mechanical properties, morphology, and thermal behavior of polycarbonate (PC)/plasticized cellulose acetobutyrate (CAB) blends were investigated to determine whether the plasticizer of the CAB modifies the miscibility of the blend and the mechanical properties of this essentially incompatible blend. In spite of the lack of transparency of the blends, both dynamic mechanical and thermal analysis results show the presence, at all blend compositions studied, of a single glass transition temperature which varies with the composition of the blend. Considering the ternary nature of the blends, we propose that plasticizer migration and the difficulty of discerning the presence of one or two peaks in a narrow temperature range may account for the observed behavior. Scanning electron microscopy confirms the immiscibility of the blends. The blends show large positive deviations of the tensile moduli from linearity and very low ductility. The reported tensile strength data are discussed in terms of several different equations for composites. This mechanical behavior is explained as a consequence of the migration of the plasticizer and of its subsequent antiplasticizing effect on the properties of the blend.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 603-610 
    ISSN: 0887-6266
    Keywords: copolyetherester ; polycarbonate ; miscibility ; phase separation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polycarbonate of bisphenol-A (PC)/copolyetherester (Hy) blends have been obtained by melt mixing over the complete composition range. After testing the lack of interchange reactions and degradation under the conditions studied, the miscibility state was studied by DSC and DMTA. The blends appeared to be miscible in the melt state. A fairly complex phase behavior was obtained in the solid state with Tg-composition plots showing a single Tg at most of the compositions but very different after the first and second scans. This was attributed to the different crystalline content of the blends before the two scans. The presence of a Hy crystalline phase and a single PC/Hy amorphous phase in all the blends, with the exception of the 20/80 composition, was verified by DMTA. Several thermal treatments showed the presence of an immiscibility range and, thus, the presence of a UCST. A LCST, which in the case of the 50/50 and 40/60 blends would be at roughly 75°C, will also probably exist. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 1055-1062 
    ISSN: 0887-6266
    Keywords: polyoxymethylene ; phenoxy ; transitions ; miscibility ; mechanical properties ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Blends of polyoxymethylene (POM) and phenoxy were obtained by melt-blending to determine their phase behavior and to determine, among others, their dynamic and static mechanical properties. The dynamic mechanical spectrum of POM showed an unusually wide peak below the melting temperature that was attributed to amorphous POM close to, and hindered by, the predominant crystalline phase. The Tg of phenoxy was constant with composition, as was probably that of POM, proving their complete immiscibility. The overall mechanical properties of the blends, however, were those of a compatible blend. The synergism in ductility observed in POM-poor blends was partially attributed to their lesser crystalline character. © 1996 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 339-348 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymethyl methacrylate-phenoxy blends have been obtained in an injection machine at different injection temperatures in order to determine the possibility of direct blending in these processing machines and also the effect that different blending levels have in the mechanical properties of these miscible blends. High injection temperatures, but in the range used in production of the components, provided fairly well homogenized blends comparable both in transparency and mechanical properties to those obtained by kneading and subsequent compression molding. Very good mechanical properties, although less transparent, were obtained when processing at low injection temperatures.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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