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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1681-1689 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A novel method for measuring the permeation of water vapor through polymer films is described. A cellulose detector film incorporating cobalt chloride in a blue anhydrous from is sealed between two pieces of test film in a specially designed cell. The cell is placed in a controlled temperature and humidity cabinet, and the disappearance of the blue color of the cobalt chloride is recorded spectrophotometrically as water vapor diffuses through the test film into the detector film. This simple method of determining water-vapor-transmission rates is more rapid than standard gravimetric procedures because of the highly sensitive detection technique.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A Cameca 3F imaging ion microanalyser has been used for the quantitative analysis of epitaxial layers of cadmium mercury telluride (CMT) and related materials on a variety of substrates. CMT has low thermal stability, readily losing Hg, and the erosion rate is unusually high. Nevertheless, satisfactory, reproducible, depth profiles are obtainable under constant erosion conditions. The positive secondary ion spectra of CMT, CdTe and HgTe are complicated by extensive interference by molecular ions and multicharged ions of the numerous isotopes of the matrix elements. The energy distributions of many of these are anomalous and the intensity varies non-linearly with primary-ion current density. It is shown that this anomalous behaviour is characteristic of the elements rather than the matrix. Wittmaack's theory of post-sputtering ionization is confirmed by demonstrating that the intensity in these cases is proportional to the square of the primary-ion current density and the effect is quantified for a variety of multicharged ions. Advantage has been taken of the low energy cut-off of these species to overcome mass spectral interferences. Examples are given of the quantitative variation of trace elements through epitaxial layers as part of an on-going analytical programme.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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