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  • Polymer and Materials Science  (5)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 203-212 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Differential scanning calorimetry has been used to follow the cure behavior of mica filled epoxy system using an aromatic diamine (4,4′-diaminodiphenylmethane) as a crosslinking agent. Both dynamic and isothermal methods have been adopted. The effect of mica on the kinetic parameters and the Tg of the cured system has been studied. It was found that mica accelerates the curing process, and decreases the Tg of the fully cured system to some extent.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 1921-1930 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of coupling agents, two silane and one zirconate, on the mechanical properties of mica/epoxy and glass fiber/mica/epoxy composites has been investigated. The results showed that tensile modulus and flexural strength and modulus values were improved by the surface treatment of the coupling agents. The property retention was also found to be better in the case of coupling agent-treated mica/epoxy samples after boiling in water for 2h. In the case of glass fiber/mica/epoxy composites, the flexural modulus and interlaminar shear strength values improved with increase in mica content, but the effect of coupling agents was not pronounced.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 56 (1995), S. 1339-1347 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of 3-aminopropyltriethoxysilane, 3-glycidyloxypropyltrimethoxysilane, and neoalkoxytric(dioctyl pyrophosphato)zirconate on thermal expansion behavior, dielectric strength, and arc resistance of mica/epoxy composites has been investigated. The addition of mica up to 30% resulted in the reduction of thermal expansion with respect to neat resin. However, the coefficient of linear thermal expansion of 30% mica treated with aminosilane was the least among the various coupling agent-coated filler/epoxy composites. Mica (30%)/epoxy composites showed the highest dielectric strength values (26 kV/mm), but the highest arc resistance was obtained in zirconate-treated mica (30%)/epoxy composite. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 32 (1986), S. 4393-4403 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Triphenylstibinedibromide and its derivatives with tribromo-, and pentachlorophenols have been used as flame-retardant additives for polypropylene. Maximum limiting oxygen index of 31.5 against 18.2 for unfilled polypropylene was obtained in a sample containing 10 phr of triphenylstibinedibromide. However, V-0 rating in UL-94 test was observed in 20 phr flame-retardant-filled polypropylene sample, while V-2 rating was obtained even at 5 phr flame-retardant level. Thermal behavior of flame-retardant-filled polypropylene was also studied in air atmosphere by thermogravimetric analysis, and an attempt has been made to correlate the flammability with the thermal behavior. The residue obtained in isothermal treatment at 450°C for 1/2 hour in air was analyzed for antimony and halogen which establishes the role of these flame retardants in vapor phase.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 1785-1801 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Structural properties of polypropylene (PP) filled with flame-retardant (FR) organoantimony compounds, viz., triphenylstibinedibromide and triphenylantimony (V) derivatives of tribromotrichloro-, and pentachlorophenols at 5-20 phr additive loading, were investigated through differential thermal analysis (DTA), and X-ray diffraction (XRD) studies. Incorporation of flame retardant in PP has decreased the melting temperature (Tm) and heat of fusion (ΔHf) of PP. Crystallization peak and the onset temperature, crystallization rate and crystallite size are also influenced by the addition of these compounds. The percent crystallinity obtained by XRD is in good agreement with that obtained by DTA. The tensile properties of the flame-retardant-filled PP are also studied, and an attempt has been made to correlate the tensile properties with that of structural changes in polypropylene. Fracture mechanism of flame-retardant-filled PP has been investigated with the help of a scanning electron microscope.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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