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  • Polymer and Materials Science  (3)
  • 1
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly[(4-N-ethylene-N-ethylamino)-α-cyanocinnamate] was prepared by solution esterification of (4-N-ethyl-N-(2-hydroxyethyl) amino)-α-Cyanocinnamic acid and by melt transesterification of ethyl (4-N-ethyl-N-(2-hydroxyethyl) amino)-α-cyanocinnamate. The melt transesterification generally yielded polymer with a number-average molecular weight of about 10,200 by gel permeation chromatography (GPC) versus polystyrene standards. The polymer was found to be amorphous with a glass transition temperature of about 103°C by differential scanning calorimetry (DSC). The solution esterification generally gave a polymer with a number-average molecular weight of about 2200 by GPC versus polystyrene standards. This polymer was found to have a glass transition temperature varying between 60 and 90°C by DSC. The infrared (IR) spectrum of the polymer made from both methods were analyzed in detail. The 1H- and 13C-NMR spectra of the meltsynthesized ethyl cinnamate derivative polymer are consistent with the reported structure.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 2899-2906 
    ISSN: 0887-624X
    Keywords: high-glass transition temperature nonlinear optical polymer ; syndioregic ; mainchain chromophore ; accordion polymers ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new main-chain syndioregic (head-to-head) NLO polymer was synthesized. The glass transition temperature of high molecular weight polymer was found to be 208°C, and the polymer has minimal weight loss at temperatures to at least 250°C owing to the incorporation of hydrogen bonding moieties and rigid bridging groups. The polymer was further characterized using nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR). The study of the nonlinear optical properties of this polymer are in progress. © 1993 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 341-348 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Magnetic resonance imaging (MRI) has been used to study solid rocket propellants and liner material. The samples studied were simulants, used mainly for safety reasons, of real systems using ammonium sulfate in place of the energetic materials. The polymeric binder was hydroxy-terminated poly(butadiene) (HTPB) reacted with isopherone diisocyanate. MRI was used to observe variations in intensity in the simulant samples due to differing percentages of solids loading. It also showed the homogeneous intensity obtained for an unfilled sample used for comparison with the 82% filled material. The liner material, HTPB and dimeryl diisocyanate, was imaged despite its relative rigidity observed from its short T2 value. Samples of poly(alkylene) oxide simulants were imaged, and various bubbles and regions of filler inhomogeneity were observed. These defects were correlated with photo-micrographs of the sample. MRI can be used to image real systems of solid rocket components. © 1996 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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