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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 16 (1995), S. 155-165 
    ISSN: 1572-9567
    Keywords: correlation methods ; dense liquids ; diffusion coefficient ; thermal conductivity ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A general procedure has been developed for simultaneously fitting any two of the self-diffusion coefficient, the viscosity (as the fluidity), and the thermal conductivity (as its reciprocal) as Dymond reduced coefficients, (D*,η*,λ*), to a simple function of the volume and the temperature for dense fluids. For example,D*=ζ1+ζ2 V r/(1+ζ3,/V r), whereV r=V[1-ζ1(T−T r)-ζ2(T−T r)2].T r is any convenient temperature, here 273.15 K. AsV r is common to the two properties, only eight coefficients, ζj and ζk are required. Such reduced transport-coefficient curves are geometrically similar for members of groups of closely related compounds. The procedure has been extended to give “family” curves for such groups by fitting a pair of transport properties for three substances from the group in a single regression. Overall, fewer coefficients are required than for other schemes in the literature, and the fitting functions used are simpler. The curves so constructed can be used for the correlation of data obtained from different sources, as well as interpolation and, to a limited extent, extrapolation. A comparison is made for a number of compotmd groups between simultaneous fits of the pairs (D−η ), (D−λ), and (η−λ)
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0789
    Keywords: Key words Polyacrylamide ; Nitrogen fertilizer ; Dicyandiamide ; Polymerized urea ; Polymer-encased urea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  High molecular weight, anionic polyacrylamide (PAM) is currently being used as an irrigation water additive to significantly reduce soil erosion associated with furrow irrigation. PAM contains amide-N, and PAM application to soils has been correlated with increased activity of soil enzymes, such as urease and amidase, involved in N cycling. Therefore we investigated potential impacts of PAM treatment on the rate at which fertilizer N is transformed into NH4 + and NO3 – in soil. PAM-treated and untreated soil microcosms were amended with a variety of fertilizers, ranging from common rapid-release forms, such as ammonium sulfate [(NH4)2SO4] and urea, to a variety of slow-release formulations, including polymerized urea and polymer-encapsulated urea. Ammonium sulfate was also tested together with the nitrification inhibitor dicyandiamide (DCD). The fertilizers were applied at a concentration of 1.0 mg g–1, which is comparable to 100 lb acre–l, or 112 kg ha–1. Potassium chloride-extractable NH4 +-N and NO3 –-N were quantified periodically during 2–4 week incubations. PAM treatment had no significant effect on NH4 + release rates for any of the fertilizers tested and did not alter the efficacy of DCD as a nitrification inhibitor. However, the nitrification rate of urea and encapsulated urea-derived NH4 +-N was slightly accelerated in the PAM-treated soil.
    Type of Medium: Electronic Resource
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