ISSN:
1572-8862
Keywords:
polymer
;
cluster
;
hydrogen bonds
;
Pt
;
Cu
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The reaction of (NBu4)2[Pt(CN)4] with Cu(NO3)2·2.5H2O and bipy in stoichiometric ratio in methanol solution yields the 2-D polymer {Cu(bipy)Pt(CN)4}∞. The influence of water molecules and hydrogen bonding on the formation of a 2-D polymeric structure versus a tetranuclear cluster from “Cu(bipy)Pt(CN)4” units is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009064715321
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