ISSN:
1434-4475
Keywords:
Boron complexes
;
Theoretical rate constants
;
Internal conversion
;
Radiative and non-radiative deactivation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Taking as a basis the completely-optimized S0 and S1 molecular geometries of selected 1,3-diketonato boron complexes the rate constants of internal conversion and fluorescence are determined theoretically. It is shown that the consideration of the accepting as well as promoting modes is essential to get a more substantiated insight into the photophysics of these compounds. An analysis of the significant modes is given.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00810851
Permalink