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  • 1
    Electronic Resource
    Electronic Resource
    Fine control of the porous structure and chromatographic properties of monodisperse macroporous poly(styrene-co-divinylbenzene) beads prepared using polymer porogens (1994)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2577-2588 
    Details
    ISSN: 0887-624X
    Keywords: poly(styrene-co-divinylbenzene) beads ; macroporous polymer ; porous properties ; polymeric porogen ; monodisperse beads ; chromatographic packing ; reversed-phase chromotagraphy ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The porous structure of monodisperse macroporous beads can be controlled by using soluble polymers with well-defined structural characteristics as part of the porogenic mixture. In general, the use of linear polystyrene as a porogen in the preparation of poly (styrene-co-divinylbenzene) beads shifts the pore size distribution towards larger pores. While a direct correlation between pore size and molecular weight of the porogen has been established, the chemical composition of the polymer porogen has no effect on the porous and chromatographic properties of the beads. These findings suggest that the average molar volume of the porogenic system is important while the miscibility of the polymer porogen with the crosslinked polymer that is formed is of little relevance. © 1994 John Wiley & Sons, Inc.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1994.080321321
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Monodisperse polymer beads as packing material for high-performance liquid chromotography: Effect of divinylbenzene content on the porous and chromatographic properties of poly(styrene-co-divinylbenzene) beads prepared in presence of linear polystyrene as a porogen (1994)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2169-2175 
    Details
    ISSN: 0887-624X
    Keywords: poly(styrene-co-divinylbenzene) beads ; macroporous polymer ; monodisperse beads ; porous properties ; divinylbenzene content effect ; chromatographic evaluation ; high-performance liquid chromatography ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The effect of concentration of divinylbenzene on pore size distribution and surface areas of micropores, mesopores, and macropores in uniformly sized porous poly(styrene-co-divinylbenzene) beads prepared in the presence of linear polystyrene as a component of the porogenic mixture has been studied. While the total specific surface area was clearly determined by the content of divinylbenzene, the sum of pore volumes for mesopores and macropores as well as their size distribution does not change within a broad range of DVB concentrations. Consequently, the size exclusion chromatography calibration curves are almost identical for all the beads prepared with different percentages of crosslinking monomer. However, the more crosslinked beads have better mechanical and hydrodynamic properties. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1994.080321120
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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