ISSN:
0749-1581
Keywords:
Hexachloroplatinates(IV)
;
Solid-state
;
195Pt NMR
;
Pt-Cl coupling
;
Magic angle spinning
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
High-resolution solid-state 195Pt NMR spectra of ammonium, potassium and sodium hexachloroplatinate(IV) and its hydrate were investigated using magic angle spinning of the sample. The isotropic part of the spectra has fine structure originating from dipole-dipole interaction and indirect spin coupling between platinum and chlorine nuclei. The fine structure was analysed theoretically, yielding the indirect spin coupling constants and their anisotropies.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260300715
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