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Crystal Structure and Formation of the Aluminium Hydroxide Chloride [Al13(OH)24(H2O)24]Cl15 · 13 H2O (1998)

Seichter, Wilhelm ; Mögel, Hans-Jörg ; Brand, Paul ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 795-797

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ISSN: 1434-1948

Keywords: Aluminium hydroxide chloride ; Crystal structure ; Tridecameric cation ; Structure of cation ; Formation ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A basic aluminium chloride with high chlorine content (basicity 1.85) has been crystallized from a concentrated aqueous solution. Its crystal structure has been determined by X-ray structure analysis. The structure contains tridecameric cations of a novel type consisting only of interconnected AlO6 octahedra. The formation of these polycations is discussed.

Type of Medium: Electronic Resource

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