ISSN:
0009-2940
Keywords:
Gas-phase pyrolysis
;
Tandem mass spectrometry
;
Carbonates
;
Alkyl migration
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Gas-phase pyrolysis of dimethyl carbonate and its mono-, di-, and trithio analogs has been performed in the temperature range from 1253 to 1404 K applying the gas phase Curie-point pyrolysis technique. Real-time analyses have been carried out by means of mass-spectrometric techniques. The possible isomerizations of the ester functions have been studied by collisional activation mass spectrometry in combination with appropriate D, 18O, and 34S labeling. It is demonstrated that methyl group migrations can be induced pyrolytically in cases where oxygen-to-oxygen or oxygen-to-sulfur isomerizations are involved; in contrast, sulfur-to-oxygen as well as sulfur-to-sulfur isomerizations apparently do not take place.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240546
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