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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 36 (1991), S. 475-490 
    ISSN: 1573-4889
    Keywords: oxidation ; mechanism ; Ti-Al alloys ; Ti-Si alloys ; nickel-based alloys
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Thermodynamic calculations are performed to estimate isothermal sections of Ti-Al-O, Ti-Si-O, and Ni-Al-O phase diagrams. Very small aluminum levels (〈10−10 at. %) are needed to stabilize alumina on Ni-Al alloys. However, much higher aluminum (≳50%) and silicon (≳40%) levels are needed to stabilize alumina and silica on Ti-Al and Ti-Si alloys, respectively. These calculations suggest that the mechanism of formation of the protective oxide films on titanium-based alloys is radically different from that on nickel-based alloys. The aluminum levels needed to form a continuous film of alumina on nickel-based alloys are dominated by kinetic factors. On the other hand, thermodynamic factors appear to dominate the alloy compositions needed to form protective films of alumina and silica on titanium-based alloys. Further work is needed to evaluate any possible role of kinetic factors.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 26 (1986), S. 397-416 
    ISSN: 1573-4889
    Keywords: Oxidation ; rare earth addition ; adhesion ; segregation ; stresses ; Auger electron spectroscopy.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract X-ray diffraction has been used to measure stains/ stresses generated in oxide films formed under isothermal conditions at 1150–1225° C and cooled to room temperature. High compressive strains, of the order of 1%, were measured in alumina films formed on FeCrAlY. However, little or no strain was measured in oxide films on NiCrAlY and NiCoCrAlY samples, even when there was no scale spallation. Auger Electron Spectroscopy (AES) experiments have also been conducted to evaluate the role of segregation on scale adhesion. Our studies suggest that the adhesion mechanism might depend on the alloy composition. On iron-based alloys, the scale spallation might be prevented by mechanisms that involve strong bonding at the interface. On the other hand, the scale spallation on nickel-based alloys might be prevented by a mechanism that relieves stresses. Yttrium segregation might help in this process.
    Type of Medium: Electronic Resource
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