ISSN:
0170-2041
Keywords:
Valence rearrangement, thermal
;
Nitrones, 1,3-dipolar cycloaddition of
;
Isoxazolines, rearrangement of
;
Aziridines, 2-acyl-
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Utilizing the spiro[adamantane-Δ4-isoxazoline] precursor 10, a key 2-acylaziridine intermediate (11) has been isolated, thus providing conclusive evidence that an initial ring contraction may be considered to be the first step of the Δ4-isoxazoline-pyrrole rearrangement.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199019900117
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