ISSN:
1572-879X
Keywords:
vanadylpyrophosphate
;
butane oxidation
;
maleic anhydride
;
catalyst
;
pairing of vanadyl groups
;
ESR spectroscopy
;
magnetic susceptibility
;
Curie–Weiss behaviour
;
Curie constant
;
Weiss temperature
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract ESR and magnetisation experiments have identified a new type of antiferromagnetic pairing of vanadyl groups in the butane oxidation catalyst vanadylpyrophosphate. This pairing is an order of magnitude weaker than the coupling predominantly found in crystalline (VO)2P2O7.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1019096409678
Permalink