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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 28 (1996), S. 111-132 
    ISSN: 1573-8868
    Keywords: discriminant analysis ; kriging ; principal component analysis ; robust M-estimation ; separation of mixed populations ; spatial trend
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Typically, datasets originated from mining exploration sites, industrially polluted and hazardous waste sites are correlated spatially over the region under investigation. Ordinary kriging (OK) is a well-established geostatistical tool used for predicting variables, such as precious metal contents, biomass, species counts, and environmental pollutants at unsampled spatial locations based on data collected from the neighboring sampled locations at these sites. One of the assumptions required to perform OK is that the mean of the characteristic of concern is constant for the entire region under consideration (e.g., there is no spatial trend present in the contaminant distribution across the site). This assumption may be violated by dalasets obtained from environmental applications. The occurrence of spatial trend in a dataset collected from a polluted site is an indication of the presence of two or more statistical populations (strata) with significantly different mean concentrations. Use of OK in these situations can result in inaccurate kriging estimates with higher SDs which, in turn, can lead to incorrect decisions regarding all subsequent environmental monitoring and remediation activities. A univariate and a multivariate approach have been described to identify spatial trend that may be present at the site. The trend then is removed by subtracting the respective means from the corresponding populations. The results of OK before and after trend removal are being compared. Using a real dataset, it is shown that standard deviations (SDs) of the kriging estimates obtained after trend removal are uniformly smaller than the corresponding SDs of the estimates obtained without the trend removal.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mathematical geology 26 (1994), S. 361-388 
    ISSN: 1573-8868
    Keywords: robust M-estimators ; influence function ; background estimation ; robust confidence limits ; separation of mixed sample
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract Samples from hazardous waste site investigations frequently come from two or more statistical populations. Assessment of “background” levels of contaminants can be a significant problem. This problem is being investigated at the U.S. Environmental Protection Agency's Environmental Monitoring Systems Laboratory in Las Vegas. This paper describes a statistical approach for assessing background levels from a dataset. The elevated values that may be associated with a plume or contaminated area of the site are separated from lower values that are assumed to represent background levels. It would be desirable to separate the two populations either spatially by Kriging the data or chronologically by a time series analysis, provided an adequate number of samples were properly collected in space and/or time. Unfortunately, quite often the data are too few in number or too improperly designed to support either spatial or time series analysis. Regulations typically call for nothing more than the mean and standard deviation of the background distribution. This paper provides a robust probabilistic approach for gaining this information from poorly collected data that are not suitable for above-mentioned alternative approaches. We assume that the site has some areas unaffected by the industrial activity, and that a subset of the given sample is from this clean part of the site. We can think of this multivariate data set as coming from two or more populations: the background population, and the contaminated populations (with varying degrees of contamination). Using robust M-estimators, we develop a procedure to classify the sample into component populations. We derive robust simultaneous confidence ellipsoids to establish background contamination levels. Some simulated as well as real examples from Superfund site investigations are included to illustrate these procedures. The method presented here is quite general and is suitable for many geological and biological applications.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electroanalysis 9 (1997), S. 1005-1008 
    ISSN: 1040-0397
    Keywords: Quadridentate dihydrogen perchlorate ; Macrocyclic membrane ; Zn2+ ions ; Baby foods ; Soft drinks ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A quadridentate dihydrogen perchlorate macrocyclic membrane is found to exhibit quite promising selectivity for Zn2+. It can be used to estimate zinc in the range 2.5 × 10-6 to 1.0 × 10-1 mol dm-3 (0.16 to 6.50 × 103 mg dm-3) with a near-Nernstian slope of ≍ 28 mV per decade of concentration. The working pH range of the sensor is 3.0 to 7.0. The polystyrene based membrane electrode is found to possess adequate stability and specific selectivity with a response time of 10 s. Most of the ions that interfere with Zn2+ electrode do not cause any significant disturbance with this assembly and the sensor can be used for more than three months in aqueous as well as in partially nonaqueous media. The utility of the membrane sensor has also been observed in solutions contaminated with detergent matter. The membrane sensor has also been used successfully to analyse some baby food products and soft drinks for the determination of Zn2+ ions.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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