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Absorption and reaction of CO2 with 2,3-epoxypropyl phenyl ether using aliquat 336 AS catalyst (1997)

Park, D. W. ; Park, S. W. ; Kaseger, C. F. ; [weitere]

Springer

Reaction kinetics and catalysis letters 62 (1997), S. 243-250

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Details

ISSN: 1588-2837

Schlagwort(e): Kinetic study ; absorption ; phenyl glycidyl ether ; carbon dioxide

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract A kinetic study on the absorption and reaction of carbon dioxide with 2,3-epoxypropyl phenyl ether (phenyl glycidyl ether, PGE) in benzene solution has been carried out at room temperature in the presence of tricaprylylmethyl ammonium chloride (Aliquat 336) as catalyst. A simple method of measuring the absorbed volume of CO2 was proposed to obtain the reaction rate constant, and it was based on the film theory accompanied by a chemical reaction. The enhancement factor (β-NCO2/NCO2 o) increased with increasing bulk concentration of PGE and Aliquat 336. The flux of CO2 was proportional to the agitation speed.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02475458

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