ISSN:
1572-879X
Keywords:
Ethyl methyl ketone
;
ultrastable Y-type zeolite
;
pentacoordinated aluminum
;
acid-base catalysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Proton exchanged ultrastable Y-type zeolite with silica/alumina = 40 showed a pronounced catalytic activity for the formation of ethyl methyl ketone directly from 1-butene and water. The formation rate of ethyl methyl ketone was much higher than those on MoO3-based catalysts in the oxidation of 1-butene by oxygen. It was suggested that the basic site necessary for the formation of ethyl ketone directly from 1-butene and water would be the pentacoordinated Al.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00764734
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