ISSN:
1572-8927
Keywords:
Conductance
;
water
;
acetonitrile
;
Walden products
;
aqueous acetonitrile mixtures
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Conductance measurements oni-Am3BuNI (TABI), NaBPh4, NaI, NaBr, NaCl, and KCl are reported for aqueous mixtures containing up to 20 mole% acetonitrile at 25°C. Experimental data were analyzed by the 1965 Fuoss-Onsager-Skinner equation. Limiting ionic equivalent conductances in water-acetonitrile mixtures were calculated assuming that the contribution to the limiting conductance foriAm3BuNBPh4 is the same for both ions involved. The trends observed for the limiting ionic conductance-viscosity products for several ions in these water-rich solvents are discussed in terms of structural effects and ion-solvent interaction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00651540
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