ISSN:
1572-8927
Keywords:
Hydrochloric acid
;
water-dioxane
;
water-tetrahydrofuran
;
water-dimethoxyethane
;
conductance
;
EMF
;
association constants
;
short range non-coulombic interactions
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Available emf data for HCl in water-dioxane, water-tetrahydrofuran, and water-dimethoxyethane at 25°C have been analyzed using models based on similar levels of approximation as was used previously for conductance data. The emf data were evaluated in terms of standard cell potentials, apparent distances of closest approach, association constants and a Gibbs energy term attributed to non-coulombic ion-solvent interaction. Although emf and conductance data give essentially the same results it is clear that the conductance method, with its much greater precision, is superior for this type of analysis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00972716
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