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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plasma chemistry and plasma processing 15 (1995), S. 221-230 
    ISSN: 1572-8986
    Keywords: C atom density determination ; gas temperature determination ; flowing post-discharge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Nitrogen, oxygen, and carbon atoms have been detected by optical emission spectroscopy in a common flowing post-discharge of an Ar-x CH4 rf plasma torch and an Ar-2%N2 microwave discharge. Gas temperature as determined from CN and N2 rotational svstems is 3200 ± 200 K in the rf torch and 700 ± 100 K in the post-discharge at a time 3 X10−2 s after the rf plasma torch. From the intensities of the N2 1st positive system, of NO, and of CN violet hands, the atom densities have been determined as 2 X 1016 cm3 for N, 1015 cm3 for O, and 6 X 1012 cm3 for C in the post-discharge at p=650 torr, with 103 of CH4 in the Ar torch.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 1015-1022 
    ISSN: 0887-6266
    Keywords: complexing polymer ; solution viscosity ; poly(glyceryl methacrylate) ; borate ion ; phenylboronate ion ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The viscosity behavior of polyelectrolyte solutions induced by borate or phenylboronate complexation with poly(glyceryl methacrylate) (PGM) has been investigated. In dilute solutions borate ions can form monodiol (1/1) complexes and didiol (2/1) intramolecular complexes. Both types of complex are anionic. Thus, the polymer is characterized by the existence of charged sites on the chain and loops formed by intramolecular complexation. On the contrary, phenylboronate can only give monodiol 1/1 complexes. In the presence of passive salt, the charges are screened. By addition of borate ion to a PGM solution, a decrease of the initial polymer viscosity due to loop formation is first observed, then the anionic charges fixed on the chain by complex formation induce an expansion of the polyelectrolyte and the viscosity of the solution increases. The situation is different for the PGM-phenyl boronate system, where no intramolecular crosslink is present. In this case the viscosity of the solution increases with phenyl boronate concentration. But for a fixed complexing ion concentration it will tend to that of the neutral polymer when NaCl is added. ©1995 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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