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Digitale Medien

Multifunctional Calix[4]arenes Containing Pendant Amide and Phosphoryl Groups: Their Use as Extracting Agents and Carriers for Alkali Cations (1997)

Yaftian, M. R. ; Burgard, M. ; Matt, D. ; [weitere]

Springer

Journal of inclusion phenomena and macrocyclic chemistry 27 (1997), S. 127-140

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ISSN: 1573-1111

Schlagwort(e): Alkali cations ; calixarene ; amide ; phosphine oxide ; complexation ; extraction ; transport

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The complexing, extracting and mobile carrier properties of the tetra(phosphine oxide)-calix[4]arene 1 and the hybrid diamide-di(phosphine oxide)-calix[4]arene 2 were studied. Both ligands give 1 : 1 complexes with alkali cations in THF as shown by the picrate method. 1H NMR experiments were run to follow encapsulation of sodium and potassium cations. The corresponding spectra indicate C2-symmetrical structure. The observed extraction orders of the alkali picrates were as follows K+〉Rb+〉Li+〉Cs+〉Na+ for 1 and Li+〉Na+〉K+〉Rb++ for 2. Transport kinetics was analysed by means of a model which assumes pure diffusion and which allows the evaluation of mass transfer coefficients in all systems. These coefficients and their influences on the transport rate are discussed in terms of size of the transporting species in the liquid membrane.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1007975928021

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Digitale Medien

Calix[4]arenes with Pendant Amide and Phosphine Oxide Functionalities: Use as Extractive Agents and Carriers for Silver (I) Ions (1997)

YAFTIAN, M.R. ; Burgard, M. ; Bachiri, A. El ; [weitere]

Springer

Journal of inclusion phenomena and macrocyclic chemistry 29 (1997), S. 137-151

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ISSN: 1573-1111

Schlagwort(e): Calixarene ; amide ; phosphine oxide ; silver ; extraction ; transport

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The solvent extraction properties towards Ag+ of5,11,17,23-tetra-tert-butyl-25,27-diX-26,28-bis(diphenylphosphinoylmethoxy)calix[4]arenes (X = CH2C(O)NEt2 (1), CH2P(O)Ph2 (2), CH3 (3), CH2C(O)Et (4))have been studied. Each ligand forms a 1 : 1 complex with silver(I). Ligand1, which bears two amide functionalities, is the most efficacious,emphasizing the crucial role played by the polar amide groups. The rate oftransport of AgNO3 through a bulk liquid membrane with this ligand ascarrier was shown to be superior to that of DC18C6, a structurally-relatedmulti-oxygen donor carrier. NMR and IR data suggest that Ag+ is coordinatedto each of the oxygen atoms in the ligand leading to an encapsulatedstructure [Ag ⊂ 1]+.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1007980931959

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