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Spin catalysis: dynamics of three-spin systems (1995)

Buchachenko, A. L. ; Berdinskii, V. L.

Springer

Russian chemical bulletin 44 (1995), S. 1578-1584

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ISSN: 1573-9171

Keywords: catalysis, spin effects, kinetics ; radical reactions, quantum beats

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The kinetic theory of a new phenomenon, spin catalysis, has been developed. This phenomenon takes place in three-spin systems, when the third radical (or a paramagnetic ion) induces spin conversion in the pair, removes spin forbiddance, and thus changes the reactivity of the first two radicals. Kinetic equations for yields of spin catalyzed reactions have been derived. Conditions for spin catalysis, values of the catalytic effect, and the kinetic behavior are discussed. A new kind of quantum beats in chemical reactions is predicted.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01151273

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