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  • 1
    Electronic Resource
    Electronic Resource
    Copper wire amperometric detector for capillary electrophoresis (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Microcolumn Separations 3 (1991), S. 141-145 
    Details
    ISSN: 1040-7685
    Keywords: capillary electrophoresis ; copper electrode detection ; amino acids ; catecholamines ; peptides ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The use of a copper wire amperometric detector for capillary electrophoresis is reported. Detection is accomplished by use of a porous glass joint, which allows amperometric detection at a copper wire electrode inserted in the end of the capillary. An anodic current is produced by a change in the copper oxide film solubility, resulting from complexation of copper ions with certain analytes at the electrode surface. This copper/copper oxide electrode has been used to detect nonelectroactive native amino acids and dipeptides. Subfemtomole detection limits in picoliter injection volumes have been obtained without solute derivatization. In addition, simultaneous analysis of nonelectroactive amino acids and electroactive catecholamines has been demonstrated.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mcs.1220030207
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Scanning electrochemical detection in capillary electrophoresis (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Microcolumn Separations 6 (1994), S. 263-268 
    Details
    ISSN: 1040-7685
    Keywords: capillary electrophoresis ; scanning electrochemical detection ; voltammetric detection ; catecholamines ; peptides ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Scanning electrochemical detection has been combined with capillary electrophoresis to increase the resolving power for closely eluting solutes. This detection mode has been characterized and provides voltammetric information for easily oxidized solutes with linear detection over concentrations in the 10-3 to 10-5 M range. Detection limits for catechols range from 360 amol to 740 amol (2.3 μM to 6.6 μM concentrations). Finally, two neutral solutes, catechol and tryptophan, co-elute under zone electrophoresis conditions, but are resolved with scanning detection.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mcs.1220060311
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
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