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  • column chromatography  (1)
  • organomercury halides  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Symmetrization of organomercury(II) chlorides using basic alumina (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 475-478 
    Details
    ISSN: 0268-2605
    Keywords: organomercurials ; symmetrization ; column chromatography ; organomercury halides ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The symmetrization reaction of organomercury(II) chlorides (RHgCl) to R2Hg and HgCl2 in toluene solution under identical conditions using a basic alumina column has been studied­in order to compare the effect of the nature of the R groups on the extent of symmetrization. The efficiency of symmetrization depends markedly on the electron-withdrawing nature of­R, varying from 90-94% for R = trichlorovinyl or phenyl to 11% for R = 2,6-dimethylphenyl.© 1998 John Wiley & Sons, Ltd.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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