ISSN:
1572-8927
Keywords:
Chemical potential
;
compressibility
;
direct-correlation function
;
multicomponent solutions
;
partial molar volume
;
radial distribution function
;
thermodynamic properties
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract General relations are presented to relate the fluctuation thermodynamic properties of multicomponent electrolyte solutions (concentration derivatives of the chemical potential, partial molar volume, and compressibility) to integrals of the total correlation function (Kirkwood-Buff solution theory) and of the nondivergent portion of the direct correlation function. Detailed expressions are given for the single-salt, single-solvent system. It appears that the direct correlation function expressions may be of more practical use in developing correlations for solution properties because, unlike the total correlation functions, terms exist which distinguish between cation and anion interactions with water and with other ions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00650532
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