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  • 1
    ISSN: 1573-2711
    Keywords: static friction ; surface force apparatus ; confined liquid lubricant ; history-dependent shear response ; deformation threshold
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract We studied the shear response of a confined lubricant layer on approach of the transition to sliding with a surface force apparatus modified for oscillatory shear. In a given experiment, we found that the transition to sliding occurred always around the same deformation amplitude although the shear stress needed to initiate sliding varied up to a factor of two depending on sample history. This suggests the concept of deformation-controlled switching from rest to sliding. The elastic spring-constant, in the stick state, weakened with increasing deformation amplitude. This decrease can be described by a power law when plotted versus the distance to a critical deformation amplitude. The build-up of solid-like behavior after sliding stopped was also gradual and was consistent with a logarithmic time dependence. We suggest a model relating the gradual decrease of stiffness to weakening of the boundary layer, specifically to destruction of some elastic links between molecules or between molecules and the solid surfaces. Static friction (the force that must be overcome at the onset of kinetic motion) is proportional to the number of such links formed during the time of stick.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 2961-2968 
    ISSN: 0887-6266
    Keywords: anchored coils ; hydrodynamic thickness ; surface forces apparatus ; interfacial rheology ; interface ; viscosity ; theta solvent ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: We study the drainage of a near-theta solvent through densely grafted polymer layers and compare to recent notions that these layers display little permeability to solvent flow at surface separations less than a “hydrodynamic thickness.” The solvent is trans-decalin (a near-theta solvent at the experimental temperature of 24°C). The polymer is polystyrene (PS) end-attached to two opposed mica surfaces via the selective adsorption of the polyvinylpyridine (PVP) block of a PS-PVP diblock copolymer. The experimental probe was a surface forces apparatus modified to apply small-amplitude oscillatory displacements in the normal direction. Out-of-phase responses reflected viscous flow of solvent alone - the PS chains did not appear to contribute to dissipation over the oscillation frequencies studied. The value of the hydrodynamic thickness (RH) was less than the coil thickness (Lo) measured independently from the onset of surface-surface interactions in the force-distance profile, implying significant penetration of the velocity field into the polymer layer. As the surface-surface separation was reduced from 3Lo to 0.3Lo, the apparent hydrodynamic thickness (RH*) decreased monotonically to values RH* ≪ RH. Physically, this indicates that the “slip plane” moved progressively closer to the solid surfaces with decreasing surface-surface separation. This was accompanied by augmentation of the effective viscosity by a factor of up to approximately 5, indicating somewhat diminished permeability of solvent through the overlapping polymer layers. Similar results hold for the flow through surface-anchored polymers in a good solvent. It is interesting to note the strong stretching of densely end-grafted polymers in a theta solvent. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2961-2968, 1997
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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