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Digitale Medien

Dynamics of contact radical ion pairs C60—aromatic amines. A study by picosecond laser photolysis (1995)

Nadtochenko, N. A. ; Denisov, N. N. ; Levin, P. P.

Springer

Russian chemical bulletin 44 (1995), S. 1038-1049

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Details

ISSN: 1573-9171

Schlagwort(e): contact radical ion pairs ; aromatic amines ; picosecond laser photolysis

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract Charge transfer complexes between C60 and ternary aromatic amines (N,N,N,N′-tetramethyl-p-phenylenediamine,p-methoxy-N,N-dimethylaniline,p-methyl-N,N-dimethylaniline,N,N-diethylaniline,N,N-dimethylaniline, and triphenylamine) were studied in chlorobenzene solutions. The lifetimes of the excited state with charge transfer in these complexes were measured by the method of picosecond laser photolysis. The dependence of the rate constant of the back electron transfer on ΔG in the back electron transfer reaction with relaxation of the charge-transfer state exhibits the “Marcus-inverted” region.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00707050

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