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Crystal structure of [Co(o-SC6H4NH2){P(OMe)3}3]PF6 (1998)

Tong, Ye-Xiang ; Kang, Bei-Sheng ; Su, Cheng-Yong ; [weitere]

Springer

Journal of chemical crystallography 28 (1998), S. 635-638

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Details

ISSN: 1572-8854

Schlagwort(e): Cobalt(II) ; 2-aminobenzenethiol ; trimethylphosphite ; crystal structure

Quelle: Springer Online Journal Archives 1860-2000

Thema: Geologie und Paläontologie , Physik

Notizen: Abstract A cobalt-thiolato-phosphite complex [Co(o-SC6H4NH2){P(OMe)3}3]PF6 has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group $$P\bar 1$$ with a = 10.590(4), b = 11.122(3), c = 13.577(5) Å, α = 101.85(1), β = 108.50(1), γ = 101.75(1)°, V = 1420.6(8) Å3, and Z = 2. The structure comprises discrete [Co(o-SC6H4NH2){P(OMe)3}3]+ cations and PF 6 − anions where the metal atom is coordinated in a highly distorted square-pyramidal environment by one chelate o-SC6H4NH 2 − (abt) and two P(OMe)3 ligands in the basal positions, and a third P(OMe)3 in the axial site with Co–N,, 1.847(5), Co–S, 2.166(2), Co–P, 2.157(2), 2.147(2), and 2.125(2) Å.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1022417127336

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