ISSN:
1572-8854
Keywords:
cyanide bridge
;
Ag···Ag interaction
;
three-dimensional structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract A three-dimensional coordination polymer [Ni(en)2Ag3(CN)5]n (en = 1,2-diaminoethane) was synthesized and characterized by X-ray crystallography. It crystallizes in the triclinic space group $$P\bar 1$$ ,a = 7.520(2) Å, b = 8.194(2) Å, c = 8.426(2) Å, α = 65.35(3)°, β = 69.57(3)°, γ = 68.91(3)°, V = 428.0(2), Å3 Z = 1. The 2D hexagonal grids are constructed using cyanides as bridges, and the Ag···Ag interactions between layers lead to a three-dimensional network.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009548705677
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