ISSN:
1572-9028
Keywords:
12-tungstophosphoric acid
;
dealuminated faujasite
;
31P MAS NMR
;
29Si MAS NMR
;
27Al MAS NMR
;
m-xylene transformation
;
liquid-phase oxidation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract 12-tungstophosphoric acid (PW12) has been supported on dealuminated zeolite Y, containing a secondary pore system with the predominant pore radii of 15 Å. The interaction between the heteropolyacid and the zeolite matrix has been studied using 29Si, 27Al and 31P MAS NMR. Distribution of two types of the Keggin anions, strongly and weakly interacting with the support, has been estimated quantitatively. Increased acidic properties of the PW12/zeolite Y system were demonstrated by a change in the selectivity pattern of m-xylene transformations in the gas phase (significantly increased dealkylation and transalkylation paths at the expense of isomerization). Redox properties were evaluated in oxidation reactions with H2O2 in the liquid phase. It has been shown that the PW12/zeolite Y catalysts can selectively oxidize a number of organic compounds at relatively low temperatures.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1027213512038
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