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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 6 (1977), S. 589-607 
    ISSN: 1572-8927
    Schlagwort(e): Lanthanum sulfate ; magnetic float densimeter ; sound velocimeter ; density ; apparent molal volume ; adiabatic apparent molal compressibility ; ion pair ; electrostriction ; hydration number
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The apparent molal volumes (φv) and adiabatic compressibilities [φK(S)] of La2(SO4)3 solutions have been determined from density and sound speed data at 25°C. The large positive deviations of φv and φK(S) of La2(SO4)3 from the limiting law have been attributed to the formation of the ion pair LaSO 4 + . The observed values of φv and φK(S) have been used to estimate the change in the apparent molal volume and adiabatic compressibility for the formation of LaSO 4 + from $$\Delta \phi (LaSO_4^ + ) = [\phi (obs.) - \phi (2La^{3 + } ,3SO_4^{2 - } )]/\alpha$$ where ϕ(2La3+, 3SO 4 2− ) is the apparent molal volume or adiabatic compressibility of the free ions, and α is the degree of association. The value of $$\Delta \phi _v^o (LaSO_4^ + ) = \Delta \bar V^o (LaSO_4^ + ) = 22.8 \pm 1cm^3 - mole^{ - 1}$$ and $$\Delta \phi _{K(S)}^o (LaSO_4^ + ) = \Delta \bar K_S^o (LaSO_4^ + ) = 85 \pm 20 \times 10^{ - 4} cm^3 - mole^{ - 1} - bar^{ - 1}$$ at infinite dilution are in reasonable agreement with the values determined from the high-pressure conductance data of Fisher and Davis. The number of hydrated water molecules (ca. 11) associated with the formation of LaSO 4 + determined from the volume and compressibility data are in good agreement.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 3 (1974), S. 91-102 
    ISSN: 1572-8927
    Schlagwort(e): Ion pair ; rubidium nitrate ; thallium(I) nitrate ; density ; apparent molal volume ; magnetic float ; electrolyte solution ; electrostriction
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Density data for dilute aqueous solutions of RbNO 3 and TlNO 3 at 25°C lead to the following equations for the apparent molal volumes: RbNO3: ΦV = 43.07 + 2.46c 1/2 + 0.15c (0−0.41M) TINO3: ΦV = 39.50 + 10.83c 1/2 − 25.46c + 26.0c 3/2 (0.03−0.25M) From these expressions and a semiempirical equation for Φv of a completely dissociated 1:1 electrolyte, values of ΔΦv for ion pair formation at c=0.10 are calculated to be+5 ml-mole−1 for RbNO 3 and+12 ml-mole−1 for TlNO 3 . Comparison of ΔΦv with the electrostriction volume effect suggests that virtually all of the electrostriction is removed in the formation of the TlNO 3 ion pair but only about half with RbNO 3 . Values of ΔΦv are in poor agreement with those estimated from electrostatic theories of ion pair formation.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Aquatic geochemistry 6 (2000), S. 1-17 
    ISSN: 1573-1421
    Schlagwort(e): lakes ; density ; compressibility ; expansibility ; conductivity ; stability ; pvt properties
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract In recent years, a number of workers have studied the stability of deep lakes such as Lake Tanganyika, Lake Baikal and Lake Malawi. In this paper, the methods that can be used to determine the effect that the components of lakes have on the equation of state are examined. The PVT properties of Lakes have been determined by using apparent molal volume data for the major ionic components of the lake. The estimated PVT properties (densities, expansibility and compressibilities) of the lakes are found to be in good agreement with the PVT properties (P) of seawater diluted to the same salinity. This is similar to earlier work that showed that the PVT properties of rivers and estuarine waters could also be estimated from the properties of seawater. The measured densities of Lake Tanganyika were found to be in good agreement (± 2 × 10-6 g cm-3) with the values estimated from partial molal properties and the values of seawater at the same total salinity (ST = 0.568‰). The increase in the densities of Lake Tanganyika waters increased due to changes in the composition of the waters. The measured increase in the measured density (45 × 10-6 g cm-3) is in good agreement (46 × 10-6 g cm-3) with the values calculated for the increase in Na+, HCO3 -, Mg2+, Ca2+ and Si(OH)4. Methods are described that can be used to determine the conductivity salinity of lakes using the equations developed for seawater. By combining these relationships with apparent molal volume data, one can relate the PVT properties of the lake to those of seawater.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 12 (1983), S. 233-254 
    ISSN: 1572-8927
    Schlagwort(e): density ; sound speed ; compressibility ; partial molal volume ; NaHCO3 ; Na2CO3 ; carbonic acid ; ionization ; pressure effects
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The densities and the sound speeds of aqueous NaHCO3 and Na2CO3 solutions were measured from 0.05 to 1.0m and from 0 to 45°C. These data were fitted to functions of molality and temperature and were used to calculate the apparent molal volumes Vϕ and compressibilites κφ of these solutions. Polynomial expression for Vϕ and κφ as functions of molality and temperature have been determined. The partial molal volumes and compressibilities of these solutions and literature data have been used to determine the volume ΔV and compressibility Δκ changes for the ionization of carbonic acid in aqueous solutions. These values of ΔV and Δκ have been used to estimate the effect of pressure on the ionization constants for carbonic acid from 0 to 45°C. The calculated pressure coefficients are in good agreement with the measured values.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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