ISSN:
1572-8943
Keywords:
calcium
;
diffusion
;
metastable defect
;
oxide ion
;
perovskite
;
sputtering
;
thin film
;
titanate
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Metastable defects of oxygen in calcium titanate thin films with perovskite structure were studied. Thin films of calcium titanate were deposited by a magnetron sputtering method. The oxygen defects were evaluated, using the results of oxygen diffusion experiments. The thin film process had tendencies of creation of a large amount of oxygen point defects and the wide range of non equilibrium solid solution at room temperature. Thecrystal distortion was increasing with deviation from the stoichiometric composition. Although the metastable defects were decreasing due to the annealing, annealed samples had more oxygen defects in a few magnitude orders than single crystals.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010125322433
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