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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 3 (1989), S. 451-457 
    ISSN: 0268-2605
    Schlagwort(e): Triorganotin compounds ; triphenyltin chloride·triphenylphosphine oxide ; diphenylbutyltin bromide ; persistence ; fungitoxicity ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The persistence of triphenyltin chloride-triphenylphosphine oxide (Ph3SnCl·Ph3PO) and diphenylbutyltin bromide (Ph2BuSnBr) in unsterilized sandy loam soil maintained in the dark at 60% of its water-holding capacity and at 27±2°C was studied over a period of 29 days. The percentage recovery of the compounds upon extraction with acetone immediately after application to soil was 60% for Ph3SnCl·Ph3PO and 9.8% for Ph2BuSnBr. The half-lives of the compounds were 15 days for Ph3SnCl·Ph3PO and 14.2 days for Ph2BuSnBr. After 29 days following application of the compounds in soil 〈 8.3 μg g-1 of Ph3SnCl·Ph3PO and 〈 5.1 μg g-1 of Ph2BuSnBr remained in soil compared with the starting concentration of 50 μg of each compound per gram soil. The two triorganotin compounds were evidently easily degraded and the compounds may be applied every 2-3 weeks in the field at a rate of at least 0.005-0.01 kg ha-1.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 3 (1989), S. 309-318 
    ISSN: 0268-2605
    Schlagwort(e): Organotins ; diphenylbutyltin bromide ; triphenyltin chloride·triphenylphosphine oxide ; soil bacteria ; soil fungi ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The effects of two triorganotin(IV) compounds, diphenylbutyltin bromide (Ph2BuSnBr) and triphenyltin chloride·triphenylphosphine oxide (Ph3SnCl·Ph3PO), on soil bacterial and fungal populations were compared with that of Thiram and the commercial triorganotin fungicide ‘Brestan’ (triphenyltin acetate, Ph3SnOAc). Soil fungal populations were reduced most by Thiram, then by Ph3SnCl·Ph3PO, Ph2BuSnBr and Ph3SnOAc, in that order. Following the application of the compounds, there was a marked increase in the bacterial population in soil, the increase being greatest with Thiram and least with Ph3SnCl·Ph3PO. The triorganotin(IV) compounds were less harmful to soil fungi than Thiram. In Thiram-treated soil, recolonization was slower than in soil treated with the triorganotin(IV) compounds. More species of fungi were tolerant to and persisted after application of the triorganotin(IV) compounds compared with Thiram. Among the fungi that were tolerant to the triorganotin(IV) compounds were cellulolytic species such as Trichoderma.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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