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  • electrodeposition  (1)
  • magnetic hysteresis  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 6 (1993), S. 185-189 
    ISSN: 1572-9605
    Keywords: Thallium cuprates ; superconductivity ; magnetic hysteresis ; irreversibility ; flux pinning
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract dc magnetic hysteresis as well as flux penetration and flux expulsion were investigated in Tl2−y Ba2CaCu2O8−x polycrystals and monocrystals. All measurements were performed at 35 K and in the 0–5 T field range. Hysteresis measurements revealed an irreversibility field of about 2 T. Existing models predict identical field-cooled (fc) and zero-field-cooled (zfc) magnetizations and vanishing time dependence above this field. Although the identical fc and zfc magnetizations are in fact observed, the time dependence vanishes only for flux penetration after zero-field cooling; a remanence is preserved after field cooling and decays with a finite relaxation rate. Activation energies calculated on the basis of the thermal activation model display a pronounced field dependence, and arelower for flux penetration than for flux expulsion in high fields (H≥3 T) for all orientations. This behavior of extreme layered superconductors contradicts classical theoretical models and questions the original definition of the irreversibility line as well. All of our results are consistent with the recent theory of lock-in transition, and can be well interpreted by using those principles.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9605
    Keywords: Thick-Film ; electrodeposition ; textured substrates ; Tl-oxides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Thick-film processing techniques such as electrodeposition, electrophoresis, spray pyrolysis, and ink spraying offer promising and economic (〈$10/kAm) approaches for fabricating high-temperature superconducting (HTS) wire or tape for the Tl-oxide superconductors. The performance of the Tl system exceeds that for the Bi-oxides and offers easier fabrication than YBCO. Scale up, however, may be difficult because of the need for open tape conductors with aligned microstructures. The Tl-oxides, moreover, offer the potential for operation at 77K in practical magnetic fields of 3-5 T, which is supported by measurements on the irreversibility behavior of the Tl-1223 single layer compound with Pb, Bi, and Sr substitution. Recent advances in the development of biaxial textured electrodeposited films on Ag coated single crystal substrates are discussed. This paper will review the merits for a near-term Tl-oxide based conductor for use in HTS electric power applications, currently under development, such as the transformer and transmission cable. Recent results for the buffer layer development that would provide an oriented ceramic layer or template on a flexible textured nickel substrate utilizing the “RABiTS” substrates developed by ORNL will then be discussed with a projection for the cost of a “long length” thick-film process using electrodeposition.
    Type of Medium: Electronic Resource
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