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Compensation Effect in the Kinetics of Spatially Hindered Phenols (1999)

Nikulicheva, O. N. ; Fadeeva, V. P. ; Logvinenko, V. A.

Springer

Journal of thermal analysis and calorimetry 55 (1999), S. 47-56

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ISSN: 1572-8943

Keywords: activation energy ; compensation effect ; enthalpy ; entropy ; pre-exponential factor

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract This paper reports a linear relationship between kinetic characteristics from the Arrhenius equation describing a decomposition process found when studying the kinetics of thermolysis of spatially hindered phenols. This relationship between the coefficients is known in the literature as a 'compensation effect'. The existence of the compensation effect permits some conclusions concerning the decomposition mechanism and thermal characteristics of the compounds under investigation.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1010171703155

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