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Crystal structure of aquo (hydroxo) (ethylenediaminetetraacetato) sodium(I) tin(IV), NaSn(OH)(edta)(H2O) (1996)

Brouca-Cabarrecq, Chantal ; Marrot, Bertrand ; Mosset, Alain

Springer

Journal of chemical crystallography 26 (1996), S. 503-508

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Details

ISSN: 1572-8854

Schlagwort(e): Tin(IV) sodium(I) complex ; ethylenediaminetetraacetic acid ; crystal structure

Quelle: Springer Online Journal Archives 1860-2000

Thema: Geologie und Paläontologie , Physik

Notizen: Abstract NaSn(OH)(edta)(H2O) is monoclinic, space groupP21/c, witha=9.747(3)Å,b=9.121(3)Å,c=16.430(6)Å, β=98.69(4)°, Å3, andZ=4. The coordination environment of Sn(IV) is a capped octahedron. Sn−O distances range from 1.990(6)Å to 2.351(7)Å. Na(I) is five coordinated to three different edta molecules. Na−O distances range from 2.283(9)Å to 2.414(7)Å. The edta ligand presents the E, G/R conformation. The crystal structure is composed of sheets parallel to (001): inside a sheet Sn(OH)(edta) molecules are connected to each other by the Na(I) interactions.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01668312

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