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  • extreme pressure lubrication  (1)
  • high temperature  (1)
  • 1
    ISSN: 1572-879X
    Keywords: molybdenum ; high temperature ; ethylene ; carbenes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reaction of ethylene catalyzed by metallic molybdenum at 875 K yields higher hydrocarbons (〉C2) with a distribution that is well described by a Schulz-Flory plot suggesting that their formation arises from the polymerization of surface C1 species. This observation is in accord with results from surface science experiments that show facile C=C cleavage in alkenes. A similar molybdenum-catalyzed reaction of propylene yields metathesis and hydrogenolysis products. In view of the product distribution found with ethylene, these products are proposed to arise from the recombination of surface species formed by propylene dissociation. This result is confirmed by modifying the Schulz-Flory function assuming equal surface coverages of carbenes and methyl carbenes which adequately predicts the measured product distribution.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Tribology letters 2 (1996), S. 221-230 
    ISSN: 1573-2711
    Keywords: extreme pressure lubrication ; pin and v-block apparatus ; temperature measurement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Interfacial temperatures attained in a pin and v-block apparatus under extreme pressure (EP) conditions were measured using pins made from either copper or an aluminum alloy from the asymptotes in the curve of removal rate versus applied load since these have been shown to correspond to the temperatures at which the interfacial material melts. The interfacial temperature rise was proportional to the applied load, where the proportionality constant α = Aμ where μ is the interfacial friction coefficient and A a geometrical constant which has been previously measured for steel pins and v-blocks lubricated by chlorinated hydrocarbons dissolved in a poly α-olefin as 2.3 ± 0.3 K/N. Values of A measured when using the aluminum alloy (2.4 ± 0.1) and for copper (2.1 ± 0.2) were in good agreement with this measurement and indicated that interfacial temperatures in excess of 1000 K can be attained during EP lubrication. Finally, the rate of material removal in the pin and v-block apparatus can be related to the metallurgical properties of the pins.
    Type of Medium: Electronic Resource
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