ISSN:
1573-9171
Keywords:
N,N-dimethylaminobenzonitrile
;
ruthenium complexes with pyridine and bipyridine ligands
;
high pressure luminescence spectra
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Pressure tuning spectroscopy has proved to be a powerful tool for studying a wide variety of electronic phenomena. In this review we present two recent examples of the application of high pressure luminescence: (1) a test of the validity of a kinetic model for the emission characteristics of molecules that emit from excited states with different degrees of charge transfer and different geometries (molecules with twisted intramolecular charge transfer (TICT)); (2) an elucidation of the mechanism for the large difference observed between the luminescence efficiencies of [Ru(bpy)3]2+ and [Ru(bpy)2(py)2]2+ in solid media.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00700881
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