ISSN:
1573-9171
Keywords:
pentafluoroaniline, aromatic trihalomethyl derivatives
;
aluminum trichloride
;
imidoyl chloride moiety
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reactions of pentafluoroaniline with aromatic CX3-derivatives (X = F, Cl) in the presence of AlCl3 were studied. It was shown that compounds with a CF3 group can be used in reactions with polyfluoroaromatic amines instead of CCl3-derivatives for the synthesis of imidoyl chlorides. In the case of compounds with several CX3 groups, the formation of the imidoyl chloride moiety predominantly involves one of the CX3 groups under the conditions studied. The introduction of a second CX3 group can be carried out only under more drastic conditions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01558072
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