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Studies of reactive intermediates using matrix and gas-phase techniques (1998)

Wentrup, Curt ; Flammang, Robert

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 11 (1998), S. 350-355

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Details

ISSN: 0894-3230

Schlagwort(e): 1,3-dipoles ; cumulenes ; infrared spectroscopy ; mass spectrometry ; flash vacuum thermolysis ; Chemistry ; Theoretical, Physical and Computational Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: In the direct investigation of reactive intermediates it is particularly valuable to use a combination of several spectroscopic techniques. This commentary highlights recent examples, using primarily flash vacuum thermolysis for the generation of the intermediates, and matrix IR spectroscopy in conjunction with gas-phase mass spectrometric methods for their identification. The examples include nitrile imines, nitrile ylides, nitrile sulfides and selenides, dinitrogen sulfide and several novel cumulenes (X=C=C=Y, RN=C=C=C=X). © 1998 John Wiley & Sons, Ltd.

Zusätzliches Material: 10 Ill.

Materialart: Digitale Medien

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