ISSN:
1572-8943
Keywords:
coordinationcompounds
;
CRTA
;
kinetics
;
polymerization
;
pyrolysis
;
quasi-equilibrium
;
TG
;
thermolysis
;
volatility
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Quasi-equilibrium thermogravimetry (variant of CRTA) is put to use as an express method of thermoanalytical screening for volatile compounds. During the experiments for P—T relationship calculations (running with several calibrated standard sample holders) the non-volatile (polymerized) residue is formed (and is decomposed with further temperature rising). Thermogravimetric data are used for the calculation of the kinetic parameters for the polymerization reaction, taking place (concurrently with the evaporation) in the melt of the studied volatile compound.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010183601559
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