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  • lecithin  (1)
  • pentanol  (1)
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  • 1
    ISSN: 1435-1536
    Keywords: Organogels ; lecithin ; self-diffusion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract We report NMR-PFGSE self-diffusion coefficient measurements of long cylindrical reverse micelles in ternary system lecithin/cyclohexane/water.1H-NMR linewidth values of the trimethylammonium signal, as a function ofW 0, at different temperatures and lecithin concentrations, were also determined. The measured water self-diffusion coefficients, $$D_{H_2 O}$$ , show a strong dependence onW 0. Both $$D_{H_2 O}$$ andD lec (lecithin self-diffusion) exhibit a characteristic dependence on the experimental time scale. An attempt to rationalize the data obtained in terms of different motional regimes is reported.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1435-1536
    Keywords: Reverse micelles ; CTAB ; self-diffusion ; pentanol ; charge fluctuation model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In the quaternary water-in-oil CTAB/n-pentanol/n-hexane/water microemulsion the role of the cosurfactant has been extensively investigated by means of spectroscopic and conductometric techniques. A detailed description of the water and cosurfactant partition between the continuous and the dispersed phase has been obtained. A complete characterization at molecular level of the modifications induced in the aggregates by varying the cosurfactant amount in oil rich region of the microemulsion at different water content has also been achieved. The alcohol concentration surely has a twofold effect on the diffusion of the aggregates varying the viscosity of the medium and modifying the interfacial composition.
    Type of Medium: Electronic Resource
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