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Roles of classical dynamics and quantum dynamics on activated processes occurring in liquids (1986)

Chandler, David

Springer

Journal of statistical physics 42 (1986), S. 49-67

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ISSN: 1572-9613

Keywords: Barrier crossing ; activation ; correlation functions ; non-adiabatic transitions ; liquids

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract This paper reviews the reactive flux correlation function approach to studying the classical dynamics of activated processes in liquids. The possibilities and consequences of nonadiabatic electronic transitions in affecting this dynamics is also considered. We emphasize the feasibility of quantitative trajectory studies and the fact that these studies have yet to be fully exploited in the development of approximate theories of activated processes.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01010840

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