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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 274 (1996), S. 899-903 
    ISSN: 1435-1536
    Keywords: Amino acids ; husks ; microcapsules ; microspheres ; self-assembly
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Solid microspheres that were phase-separated in aqueous suspensions of thermal heterocomplex molecules made by heating a mixture of proline and aspartic acid transformed into husk-like microcapsules as pH increased. The transformation from solid microspheres into microcapsules proceeded at two different time scales. Rapid dissolution of thermal heterocomplex molecules from the outer surfaces only during a short period was followed by slow dissolution of those molecules from their inside. The difference of the rates of dissolution led to the formation of microcapsules carrying smaller inner kernels as remnants.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 275 (1997), S. 502-505 
    ISSN: 1435-1536
    Keywords: Key words Amino acids ; diffusion ; husk ; microcapsules
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  Solid microspheres consisting of thermal heterocomplex molecules made from heating a mixture of aspartic acid and proline were transformed into husk-like microcapsules in their aqueous suspensions when pH value increased. The thickness of the outer shell of the husk-like microcapsule decreased as pH increased. Formation of the husk-like microcapsules is discussed to be due to both diffusion of the constituent molecules from the inside of the microspheres and conformational changes of those molecules in the process.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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