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  • 1
    ISSN: 1435-1536
    Keywords: Semi-Crystalline Polymers ; orientation ; crystallinity ; magnetic coating ; processing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A combination of structure identifying and bulk property experiments were combined with a two-phase analytical methodology to elucidate the influence of a magnetic tape coating process on the substrate polymer film. Employing a typical tape manufacturing process that utilizes coating, drying, and calendering stages, polyethylenete-rephthalate polymer film samples with and without the magnetic coating were prepared. Experiments and modeling studies performed on these samples demonstrate that the drying and calendering processes may increase the crystallinity and noncrystalline orientation of the substrate film. In addition, dynamic mechanical experiments identified a viscoelastic transition at 50 °C for the PET substrate film sample which is near the glass transition of the magnetic coating utilized. Overall, the results of this investigation provide a basis for evaluating structure property interrelations of polymer-based magnetic tapes.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 62 (2000), S. 599-608 
    ISSN: 1572-8943
    Keywords: microscale heat transfer ; micro-thermal analysis ; thermosetting polymers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Glass transitions of amorphous polystyrenes with low polydispersity were evaluated using the modulated Local Thermal Analysis mode of the TA Instruments 2990 µ TA and evaluating the thermomechanical signal. Transition temperature variance and fraction of transitions measured were compared for high molecular mass thermosetting materials and the melt of Nylon 6.6. The transition reproducibility was found to decrease as the molecular size of the polymer samples increased. Reproducibility also decreased for thermosetting materials when the experimental ramp rate was decreased. Heat transfer within the specimen was evaluated using finite element analysis, allowing scaling of microscale experimental results for comparison to bulk transitions.
    Type of Medium: Electronic Resource
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