ISSN:
1573-4846
Keywords:
nuclear wastes
;
aerogel
;
chemical durability
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract For long life nuclear wastes (essentially actinides) research is in progress to propose new matrices with an improvement of the chemical durability. High silica content glasses present high chemical durability, and we describe a process to prepare silica glass embedding the nuclear waste. Porous silica (gel) is used as a host matrix for nuclear waste. Neodymium oxide and cerium oxide are used to simulate the actinide oxides. The gel is soaked in a solution containing the simulant in nitrate salt form. We investigate the effect of the porous network features (pore size distribution) on the ability of the material to soak up the simulating salts. A new kind of gel (composite aerogel) is proposed owing to its large permeability. After drying and nitrate decomposition, the composite material is fully sintered trapping the nuclear waste. The glass-ceramic materials (silica glass + simulating oxide) have been synthesized with simulant content close to 20 weight percent. We show that the 2 simulant oxides behave differently because of their ability to form silicate phases. The chemical durability of the glass-ceramics is investigated. The large improvement of the chemical durability (60 times) compared to the classical borosilicate glasses shows that this containment process can be a suitable way to confine actinides and long life nuclear wastes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1008784822052
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