ISSN:
1572-9028
Keywords:
strong acid
;
metal carbonyl
;
copper
;
silver
;
gold
;
carbonylation
;
olefin
;
tert-alkanoic acid
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Recent advances on metal carbonyl cations and their catalytic activities are reviewed and discussed in relation to the property of M–CO bonding. In strong acids, the carbonyl cations of monovalent copper, silver and gold catalyze the carbonylation of olefins, alcohols, dienes, diols, aldehydes and saturated hydrocarbons at room temperature and atmospheric pressure to produce tert-alkanoic acids in high yields.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1019158221240
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